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Beilstein J. Org. Chem. 2008, 4, No. 2, doi:10.1186/1860-5397-4-2
Graphical Abstract
Figure 1: (–)-Indolizidine 167B.
Scheme 1: Reagents: i Rh4(CO)12, 30 atm CO:H2 = 1:1, 125 °C, toluene, 24 min, 76% yield; ii the same conditio...
Scheme 2: Stereospecific interconversion of the rhodium-alkyl intermediates as the key for regioselective for...